Fabrication of MXene (Ti2C3Tx) based conducting polymer materials and their applications as anticancer and metal ions removal from wastewater
Huanggen Yang, Qi Zheng, Pei Zhang, Guochao Nie, Tariq Ali, Saleem Raza
Journal:Surfaces and Interfaces
IF:6.14
DOI:10.1016/j.surfin.2022.102493
PMID:
Published:2022-12-01
research field:肿瘤学生物医学工程呼吸生物学环境科学纳米技术化学材料科学
Abstract
A new types of 2D MXene based conducting polymer materials was constructed by in-situ polymerization techniques. In addition, the MXene (Ti 3 C 2 Tx) was synthesized with the combination of Ti 3 AlC 2 and HF, after successful preparation of Ti 3 C 2 Tx then, their surface was functionalized with glycidyl methacrylate (GMA) and formed the Ti 3 C 2 [email protected] Further, the Ti 3 C 2 [email protected] is combined with polyaniline (PANI) to form conducting polymer grafted thin film nanosheets named Ti 3 C 2 [email protected] /PANI with a thickness in micrometer size through the grafting method. The prepared materials were characterized by SEM, FTIR, XRD, XPS, and EDX techniques. To check the performance of materials, the in-vitro anticancer activities were performed with laser and without laser. Ti 3 C 2 [email protected] /PANI-treated cancer cells exposed to an 808 nm laser (0.48 W cm 2 , 10 min) showed a significant anticancer impact, and practically all anticancer cells were destroyed. The MTT findings demonstrating the effective in vitro anticancer impact of Ti 3 C 2 [email protected] /PANI were supported by the Calcein AM/PI double staining examination. Additionally, an adsorption investigation was conducted using the metals Cr 3+ and pb 2+, and the maximum adsorption reached 303.3 and 201.6 mg/g, correspondingly. The recovering study was also conducted, and Ti 3 C 2 [email protected] /PANI nanosheets can be easily recycled and regenerated after ten successful recovering recycle. It is anticipated that the developed process for making the MXene and conducting polymer-based Ti 3 C 2 [email protected] /PANI nanosheets would be usable for various other advanced applications.
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